If you have a reason to use FoundationDB over HDFS, NFS, S3, etc, then this will work well.
Doing a Lucene+DB implementation where each entry posting lists are stored natively in the key-value system was explored for Lucene+Cassandra as (https://github.com/tjake/Solandra). It was horrifically slow, not because Cassandra was slow, but because posting lists are optimized and putting them in a generalized b-tree or LSM-tree variant will remove some locality and many of the possible optimizations.
I'm still holding out some hope for a hybrid implementation where posting list ranges are stored in a kv store.