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You could even configure Windows 95/98 to boot directly to DOS by setting BootGUI=0 in MSDOS.SYS, and then you'd have to run "WIN" to boot Windows

Isn't MSDOS.SYS a binary? Are you sure you don't mean CONFIG.SYS?

According to Wikipedia, it became a configuration file in Windows 95 (MS-DOS 7.0): https://en.wikipedia.org/wiki/MSDOS.SYS

Interesting, never knew that.