PHP On Pie takes a fresh new approach.
I came up with its design after using a lot of other PHP frameworks, including Cake (RoR clone basically), symfony/agavi, CodeIgniter, Kohana and Zend. And drupal. I think PIE really tries to take advantage of the PHP way, and make things simple. If you want, you can drop classes from ZF or PEAR into it and they "just work". Anyway if anyone wants to get involved, drop me a line.
http://phponpie.com