But be sure to protect them, and be aware that most commercial li-ion chargers and off-the-shelf protection circuits are designed to maximize short-term battery life. They'll charge to 4.2V, and many won't cut off until 2.5V.
Also know what to do if they short and catch fire; have an appropriate extinguisher and a plan for quickly getting failed cells outside and onto an inert surface like concrete.
If you want to make a 'powerwall' whose batteries could last you for a significant amount of time (e.g. decades), you'll also probably want to design your own charging and undervoltage protection circuits.
There's some good information here: http://batteryuniversity.com/learn/article/how_to_prolong_li...