See: http://www.ipa.go.jp/security/rfc/RFC2246-AFEN.html
Search down for Diffie-Hellman.
The Wikipedia article might also be useful:
Asymmetric key encryption is slow, and symmetric is fast, so we use the former to set up the conditions necessary for the latter: If we both have a box and keypair like this, then you can send me your secret phrase using mine and I can send you my secret phrase using yours. Now that we each know both secret phrases and nobody else knows either, we can combine the secret phrases and switch to symmetric. That's how SSL is set up.
Is the term 'asymmetric key encryption' meaningful, or did I just make that up?