No, again DST changes clock time, not agreed times of work (which vary by industry anyway).
Suppliers aren't going to shift their hours if their clients don't. Investment banks won't shift if the stock exchanges don't. There'd be no change since nobody could go first.
It's much simpler to decree the change on the clock than try to convince everyone to change their schedules in lockstep.
Again, I don't like DST. I wish my area would stay on "summer time" all year. Basically shift to the next time zone. But DST is better than the ad hoc solution that you're suggesting.