The reason why accessible users use JAWS is that it works across the entire OS and all the programs you have installed; start menu, PowerPoint, web browser, control panel, Google, etc. etc. The problem with the native accessibility tools is that it fragments the accessibility experience; you have one tool for OS operations, another tool for browser work, another tool for this, etc.
So that being said - it is a waste of time to target the native APIs for accessibility. Your target is JAWS and that's it. In fact, I'd argue that JAWS is better at reading HTML than native apps, so Slack is doing the right thing by moving all their apps to the cross-platform one.