Because, at least according to a handful of VCs at DFJ, 70% of the work they do involves interacting with and convincing other people (usually people who can help their portfolio companies in some way, shape, or form).
In general, MBAs are better at this than those with technical training.
Further, a VC doesn't have to understand the intimate technical details of an opportunity to recognize that it is a valuable opportunity.
I'm not saying this makes for a good relationship with your VC, but that's why the equilibrium set of employees tends towards MBAs instead of PhDs.
However, I think you'll find that many VCs in the top-tier did engineering at undergrad, then got an MBA.