so basically the explanation is simple. There is a whitelist of protocols you can have your WebExtension take over.
If the protocol you want to control is not on that whitelist such as an hypothetical "catgifs:" protocol, you need to prefix it like: "web+catgifs" or "ext+catgifs" depending if it will be used from the Add-on or by redirection to another Web page. This makes it inconvenient to use with lots of decentralization protocols because in many other clients we are already using urls such as "ssb:" and "dat:" (eg, check out beaker browser). In essence this allows us to implement many new cool decentralization features as add-ons now that we can take over protocols, so, you could be in Firefox browsing the normal web and suddenly see a "dat:" link, normally you'd need to switch clients to a dat enabled app, now, you can have an add-on display that content in the current user-agent you're using.
Still, there is another feature that we need before we can start really implementing decentralization protocols as pure WebExtensions, we need both TCP and UDP APIs like we had in Firefox OS (as an example, Scuttlebutt uses UDP to find peers in LAN and its own muxrpc TCP protocol to exchange data, DAT also uses UDP/TCP instead of HTTP).
I have been building little experiments in Firefox for interfacing with Scuttlebutt which can be seen at:
https://viewer.scuttlebot.io/%25csKtp9VmxTjJoKy17O7GA6%2F3S8...
https://viewer.scuttlebot.io/%25uBev5w8m8iZGVbQDo9fpr%2BCXLB...
I hope to start a conversation in the add-ons list about TCP and UDP APIs for WebExtensions soon :-)