What are the best uses of document stores?
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http://couchapp.couchone.com/focus/_design/focus/index.html#...
For more info on the method of serving HTML5 apps directly from CouchDB's web-server: http://couchapp.org/page/what-is-couchapp
I keep PostgreSQL for many things, but the "business related" data are stored in Mongo. This is running pretty well and it makes the agile part of the development easy, as one have nearly no impedance miss match between the code and the storage (the MongoDB drivers return ordered dictionaries and lists and I can access them from Python and PHP easily).
I was definitely faster from "idea to market" with Mongo.