A reflection with just 1 microsecond delay would require a 300 meter reflection path (e.g. 150 meter to/from the reflector). I think you might be thinking of multi-path propagation within the context of long-distance communication (e.g., a HAM QSO).
A regular home Wi-Fi network is already a complex multi-path system, as the primary propagation mode is reflections from walls and ceilings, leading to plenty of self-interference with many hot- and cold-spots from constructive and destructive inteference. We are at most introducing a few stronger reflections in an already extremely reflection-heavy environment. The big question is whether it does any good, either through attenuation or gain.
As for MIMO, I must admit to not knowing much about it—I know it utilizes spacial separation to increase bandwidth, but I do not know much of its actual implementation, and thereby weaknesses.