Face only? Face and arms? Entire upper body? Entire body?
Is there some online resource for this with time of year and latitude corrections? I imagine there's quite a difference between vitamin D production in noon sun in Fairbanks Alaska versus Miami Florida.
"John Jacob Cannell, MD, executive director of The Vitamin D Council, notes that the skin makes 10,000 IU of vitamin D after 30 minutes of full-body sun exposure. He suggests that 10,000 IU of vitamin D is not toxic."
https://www.webmd.com/osteoporosis/features/the-truth-about-...
[1]: http://www.sciencefocus.com/qa/can-you-absorb-vitamin-d-thro...
I do remember reading years ago about a sanitarium in the late 1800's - early 1900 where the windows in the sun rooms were quartz glass.
I would /guess/ that pure (greenhouse?) glass, maybe not even visibly transparent, would be effective.
Both could be worth studying if someone hasn't already.
There exist optically transparent plastics that do not.