"use of an impossible probability distribution" - this sounds interesting. Which exact distribution do you mean? To me it seems (though I might be wrong) that the distributions are perfectly valid.

You have a pair of random variables (X, Y) that take values (100, 200) or (200, 100) with equal probability. Then E[X] = E[Y] = 150, there is no question about that. Also, E[X/Y] = 1.25, there is also no question. The only question is why E[X] is useful and E[X/Y] is not useful for our decision making - and I honestly don't know why.