kqueue is on OpenBSD and FreeBSD, while epoll is from Linux. (poll and select are on both)
There are probably hordes of people who will be willing to run Mongrel2 on *BSD platforms, precisely because of the performance reasons. And Zed is a famous tinkerer rather than a religious zealot, so very probably he could be interested in checking kqueue as well.
"Why not" is also a good reason for a hacker when he's lacking other reasons.