BSD doesn't have drivers for Infiniband and other HPC interconnects. Nor does it have client drivers (let alone server implementation) for Lustre which is the distributed filesystem used by most super computers.
I imagine MPI support on BSD is also likely non-existent. Then there is the matter of accelerator support, i.e NVidia GPUs and Intel Xeon Phi.
It's not to say that some vendor couldn't reasonably build a BSD based supercomputer, it's just highly unlikely given how much stuff is missing.