The main problem with RSS is that it is simply not
discoverable.
The related UX problem is that major browsers didn't have a built-in reader, so there is nothing with which to discover RSS.
To use RSS, you have to get some add-on like Brief for FireFox, or third-party app for Android. Or else use some website like Google Reader (I think that's dead now?).
Before you do that, in the first place, you have to know what the heck RSS is, and what are the benefits: why should you be installing this additional stuff for interacting with some hidden aspect of the web.
Browsers need to make it discoverable by alerting users, like by bringing up a bubble: "Hey, user! This web page's updating listings are available in a condensed RSS feed [learn more.] You can register the feed into my built-in feed reader, and then not only browse the items conveniently, but be alerted of new ones, search through the items, and delete ones you don't want."*
When we were recently looking, on Craigslist, for a bunch of different types of items simultaneously, I showed my wife RSS. From the beginning: how it is the condensed version of a web-site, and how you need a program to deal with it (went through an installation of Brief on Firefox). Then how you add feeds to the reader, and go look at them through the Brief toolbar button, etc. Then configuration: explaining how Brief just surfs the RSS periodically the same way that a human being refreshes a web page, and that the frequency can be configured, as well as how long the items are stored.
So after that she was using it daily, no problem, and mostly liking the convenience of just checking the feeds for what has dripped in, and being able to erase the duds, as if it were an e-mail inbox.