KL divergence minimization (variational inference) is typically a weak approximation to the model you specified. I have seen it produce inferences on simulated which are just plain wrong. These "wrong" models are still often good predictors, so whether variational inference will work well for you depends on whether you care about making valid inferences or just doing prediction.
My problem was that I couldn't identify the coefficients. So for instance, the first principal component could be [x, x, x, ...] or [-x, -x, -x, ...] and the result would be some bimodal distribution. So if you placed restrictions on the first PC it would work (like only positive), but those restrictions may not make sense for the next PCs.
This thread has some good examples of PCA implementations in STAN. https://groups.google.com/forum/#!topic/stan-users/5R2-QUDiy...