The W3C document[0] has a few suggestions:
> A Web application provides input for a smart home system to control lighting.
> A Web aplication checks whether light level at work space is sufficient.
> A Web application calculates settings for a camera with manual controls (apperture, shutter speed, ISO).
> A Web application monitors light level changes produced by hovering hand user gesture and interprets them to control a game character.
While these applications are all potentially valid, it seems like each use case would be better served by a native app.
[0] https://www.w3.org/TR/ambient-light/#usecases-requirements