We currently have 9.6 with barman for streaming backups and repmgr to control replication. Compared to any of our MySQL setups is a breeze to manage, my team is owning both and the bad thing is that there was only one issue so far[1] on call (bad, because if system doesn't break often no one will learn about it).
PostgreSQL + barman + repmgr is much nicer than anything else we have for MySQL.
Few things: barman offers streaming backup, meaning it is not just once a day, but it is done continuously. On top of that contains a single command that can verify it operates correctly (it has enough backups, streaming operation works etc).
I also like that everything is robust. In MySQL if replication breaks, I need to manually restart it, if it gets too far behind (too many changes, or it is not fixed fast enough) the wal logs will be erased and I would need to set it up from the scratch again[2].
Postgres is smart enough to keep track of all wal logs and only deletes them if all standby nodes received them. If connection is broken (for example a network partition) it will reconnect and resume replication. It self heals whenever it cans. It is a breeze to manage.
Another thing MySQL lost a lot of points for me was at my previous workplace. An MySQL host suddenly started throwing errors to clients. Turns out that few tables got corrupted, the fixing was easy, just shutting down and running repair tool. What was puzzling is that there was no obvious reason (the disk had plenty of free space, no corruption) the machine was not abruptly terminates (~100 days uptime) I never found why data got corrupted. Also, I never experienced things like that with Postgres.
[1] the issue was that barman host had a bad disk, so that triggered an alert and after disk replacement things continued to work.
[2] there is also one crazy system that MySQL allowed to happen. Essentially in master-standby replication someone had genius idea to do some processing on the data in master and write it in standby. Over time that data became also important, so actually the standby node needed to be backed up instead of the master. This is "great" because if replication breaks, whomever is on call will have fun time doing some acrobatics to restore the whole thing. Postgres correctly doesn't allow writes to standby during replication.