Sure there are people who will express dissatisfaction with Excel. And many many use cases for which Google's product is good enough. But it is all the edge cases that Excel covers that makes it viable to standardize upon across a user base where some users have a significant level of expertise and that expertise is diverse.
To put it another way, free and available anywhere and easy collaboration are all great features. But they are not enough. Killer features will only become killer once a spreadsheet does pretty much everything Excel does (and in pretty much the way Excel does it so that muscle memory works).