I've used Postgres and Mongo pretty extensively, and for any reasonably seasoned developer, the startup overhead of an SQL system is a myth. There may upfront cost to learning how an RDMS and SQL work in the first place, but once you're familiar with them, they'll be faster than Mongo on any new project.
The schemaless concept of a document database seems to be the major selling factor in velocity of movement, but once you've got a good handle on a migration framework in the vein of ActiveRecord or other popular software, that's negated completely. It also really doesn't take long before schemaless starts to cause big problems for you in terms of data consistency -- it's not just the big players that get bitten by this.
The simplified query language is another one. SQL is a little bit obtuse, but it's not that bad once you have a handle on it, and a lot of people are familiar with it. Once you add in an ORM layer, the lazy-style access of a framework like Sequel or SQLAlchemy makes the developer experience quite a bit better than any Mongo APIs that I've seen. Also, after you get beyond trivial usage, SQL's flexibility so wildly outstrips Mongo's query documents that it's not even worth talking about.
Postgres on the other hand ships with a great management CLI, a very powerful REPL (psql), and features like data types/constraints/transactions that guarantee you correctness with zero effort on your part. I can only speak for myself, but I'd take Postgres to the hackathon any day of the week.