‘Instantly rechargeable’ battery could change the future of electric automobiles
purdue.edu
purdue.edu
For a large percentage of common use cases this is not an issue. EV drivers by and large do other valuable things while their vehicles charge, like work and sleep.
> Current electric cars need convenient locations built for charging ports.
This is only true for apartment dwellers (for now). People who live in houses typically charge at home.
> Designing and building enough of these recharging stations requires massive infrastructure development, which means the energy distribution and storage system is being rebuilt at tremendous cost to accommodate the need for continual local battery recharge
> Users would be able to drop off the spent electrolytes at gas stations, which would then be sent in bulk to solar farms, wind turbine installations or hydroelectric plants for reconstitution or re-charging into the viable electrolyte and reused many times.
How is this fueling and distribution system cheaper or more efficient than the grid plus a bunch of 240v/60a outlets, most of which are already available in home garages. If instant refueling is a really a dire need for someone, they can just get a plugin hybrid (i.e. Chevy Volt) and no new infrastructure needed at all.
Edit: removed snarky words
In Germany, over 65% of people rent. So, the supermajority would be affected by this.
EDIT: I meant "live in rented apartments". "Miete" implies renting an apartment here, usually.
Wait a minute, it's Germany, don't y'all already have 220V/240V/whatever it takes? In which case, yeah, I guess you could just plug into an outlet and charge just as quickly as I do in my American garage with its special charger because our outlets are 110V.
http://www.lenntech.com/processes/disinfection/regulation-eu...
While some countries moved away from permanent chlorination, it is still widely used, either as a permanent (all the way to the faucet) or punctual (just in the treatment facility) water disinfection solution.
The UK, for example, uses permanent chlorination.
So depending where you live, maybe its time to find all tap water gross.
Pretty sure I'm right in saying they don't flouridate the water either.
The downside is that it requires a highly precise tuning and maintenance of the water systems to avoid any contamination downstream. Most countries don't seem to have the discipline to do so (US for example).
But they do fluoridate the water, depending on the country and region.
Water fluoridation's positive impact is small when the population frequently brushes their teeth with fluoridated toothpaste, and both fluoridation and chlorination don't have any negative impacts on health.
Chlorinated water is used in Germany depending on the city and source. Cities using aquifers for drinking water, like Berlin, usually require less disinfectants as the original water carries little to no organisms.
They might still use chlorine for emergency disinfections. But usually the levels are very low and hard to notice.
http://www.evoqua.com/en/brands/Wallace_and_Tiernan/Pages/be...
Cities that don't have good aquifers usually resort to rivers and lakes, requiring heavier disinfection both at the treatment and on the way to the homes, so they need to add higher levels of chlorine.
All cities I've ever lived in, or ever been to, have used aquifers for their drinking water, and have never fluoritdated or chlorinated their water due to that. We currently use UV desinfection where I live.
Yeah, if you use rivers and lakes I could understand it, but I never actually knew places would do that.
https://en.wikipedia.org/wiki/NEMA_connector#/media/File:NEM...
Nope, because then you need bigger wires, and copper ain't cheap. Whereas on the same wires if the voltage is bumped, you get a wattage bump, too. So Europe gets kettles that heat twice as quickly as U. S. kettles.
Actually, we have up to 400V/60A for stoves and charging cars, or as main line for your apartment. But if you rent an apartment, you won't have that at your parking space.
The only one predicting anything is you, Captain Pedantic. Parent used the present tense, which I take to mean that if I look for an apartment today in Germany, I won’t find an apartment with a charger. Tomorrow? Who knows, no one was talking about tomorrow. On top of that, speaking from a German perspective, odds are that English is a second language. But you go right ahead and pick apart that sentence for something to criticize.
What about people who only have street parking without a driveway or garage?
If I understand correctly, this technology is a (perhaps better/more robust) flow battery into which one pumps fresh electrolyte after removing "discharged" electrolyte.
We now pump and convey by ship, rail and truck, liquid fossil fuels. Fresh electrolyte would be handled likewise.
The return loop for used electrolyte is already there. Gas trucks now return empty for refill. In many cases, an empty ship or train returns to a fuel source for refill. These could bring electrolyte back to recharging facilities. Whether these are powered by renewable or nuclear or other energy wouldn't impact the distribution system much.
Repurposing the existing fuel distribution to handle electrolytes doesn't seem prohibitive. It's something I hadn't considered, as I'm not used to thinking of electrical energy as a liquid I could deliver in a truck.
A lot of refined petroleum is shipped by pipeline. If you live in, say, the DC area, then your gasoline is coming from crude oil refined somewhere in Texas or Louisiana and shipped by pipeline to a distribution terminal. The refuelling trucks are only traveling from the distribution terminal, maybe 20 miles or so, not all the way to the refineries.
According to <https://www.rita.dot.gov/bts/sites/rita.dot.gov.bts/files/pu..., pipelines carried 63.3% of refined petroleum products in 2009, and an even higher share of (79.8%) of raw crude oil. The numbers for crude are likely to be rather different for today thanks to the Bakken oil field (which happens to not be in a conducive place for the existing pipeline network), but I don't think that refined petroleum products are likely to be very different.
Charging EVs via the grid involves minimal new distribution infrastructure. The grid already supports high loads like the kind that EVs impose and the nightly pattern of EV charging actually complement wind as an energy source.
Flow batteries seem much more promising as utility scale storage for intermittent renewables.
Even still, between time of use rates and smart charge scheduling, much of the EV charging load can be dispatched in such a way that actually postpones or mitigates altogether the need for grid upgrades.
[1] http://et.epri.com/Communications_Potential_Impacts_of_Vehic...
I also really enjoy the one-pedal-driving enabled by the "L" mode, which tells the car not to mimic an automatic, rather to use regenerative braking as aggressively as possible. I can drive all over town without touching the brakes.
I haven't driven a Leaf myself, but I know people who have, and they much prefer the Bolt EV.
I'll try to keep an eye on this thread if you have any specific questions.
For another, it's small inside, especially horizontally. It's not a big deal for me, but two large people side by side would be quite close together.
The gauge cluster screen is a bit boring, it seems like it could be more attractive and interesting. But that's a minor quibble.
Nothing else comes to mind, it's mostly been an excellent car so far.
Having stations built in convenient locations means that you can greatly extend your effective range. If I have a car that can drive for 80 miles, then I can only go 40 miles away before reaching bingo 'fuel'. Often, one will leave some buffer.
Doesn't matter if you are picking up someone at the airport, grocery shopping or working. If charging stations are everywhere, then you would only need to worry about how far you can go.
If said stations were also wireless, then one might not have to stop to charge at all.
If I could drive down the street and replace my electrolyte, neither changing jobs nor moving would suddenly make an electric vehicle unusable.
If you want to protect yourself against both a job change and a home change, well, sure, a new job and a new apartment might not offer charging.
I often drive more than the range of a Tesla and certainly more than the range of something like a Leaf, which is why I have not considered buying one.
I'm remodeling a house and putting in 240 just for the dryer an an unusual French range. Why would I need that in the garage? I certainly won't have that long an extension cord.
Certainly no one in an apartment building!
someone needs to create self-driving mobile supercharging units - just call one up to meet you somewhere
QED.
Off topic: That's interesting to know. In Europe (UK) where 240V (well more like 230V these days) is the standard, it's not uncommon to see professional workmen using step-down boxes and 110V power tools for safety reasons.
I could imagine that some professional might use a specialized tool in a niche where only a 110V version is available -- but I've never heard of that either.
The safety aspect sounds odd -- 230V is not that dangerous, especially considering that ground fault circuit breakers are mandatory. Accidentally touching a live 230V wire doesn't really hurt that much.
This blog post lists the reasons professional builders in the UK could use 230v and an RCD but generally dont.
https://www.its.co.uk/blog/buying-guides/what-is-110v-do-we-...
It looks like there's another important safety feature: the center of the output side of the transformers is connected to ground --> this means that you have two phases that both have only 55V to ground.
I imagine that accidentally touching an exposed wire with a voltage difference of 55V is a lot less dangerous than 230V.
I love HN. You learn new stuff every day.
So no, supercharging does not take hours.
Keep in mind that most people mostly don't drive most places -- they drive relatively popular routes between cities, which are well-covered by the supercharger system.
I suspect most Tesla owners might be a bit miffed when told supercharging takes hours -- it never does -- and then are told that it's unlikely that trips outside major cities will have any superchargers available -- when they are for the most popular routes.
I totally get that not every route has coverage. But these are questions of fact: unlikely is < 50%, and Tesla passed that level of coverage several years ago.
Texas has, I think around 16 Superchargers; that's one Supercharger for every 1.7 million people in the state, about a thousand times less than the number of gas stations. There are extremely large portions of the state without Superchargers and inter-city driving wouldn't really be practical. Even in a gasoline powered vehicle the distances between stations can be over 100 miles (I'm thinking of the highway that crosses the King Ranch, but that's not the only long stretch).
1. driving to a relatives 2. driving somewhere for vacation
There are also Chargepoint stations in many public parking lots, but we've never had to use them.
It's not as convenient today as gas stations. But Tesla has been adding Superchargers quickly.
BTW the same discussion happened in the mid-2000s with smartphones. People were apparently ridiculous for giving up week-long battery life for something that has to charge at least daily. Yet for many, the benefits outweigh the costs. Smartphone battery life isn't ridiculous. It's just a better fit for some people than for others.
Let's consider a trip of 300 miles. It'll cost you about $150 with your own combustor. Renting a car costs about $50/day (or cheaper, depending on which car to go for). Gas consumption will add another ~$35 which leaves you with a total of $85/300 miles.
Just curious: how often do you exceed the 100 miles range?
I always did at worst a single one-hour stop, because it's simply unhealthy not to do so. I calculated that on this route in a Chevy Bolt I would have to do four stops, and in a 85kWh(or better) Tesla - three. That's three and two more stops respectively. On one hand that's a lot, on the other I could simply take a nap then or get something to eat.
My point is: it's entirely doable with an EV today. Even better: I've seen people do it.
There are plenty of houses out there that use on-street parking.
Simple. The grid - electricity transmission and especially distribution networks (depends on how they are classified at your location) are most likely not designed to sustain the load. There are multiple problems here.
First, not sure about US, though, distribution networks are usually overcommited by some factor (sometimes hundreds of percent). It works only because urban end users in a community do not utilise their line to the max all at once. Plug in whole suburban neighbourhood full of EVs for a night and quite likely will see power outages. Oops.
Second, the problem is not as simple as "more copper = more load". Mainly the grid must have some level of redundancy - single home unit is reached from power plant via multiple paths, so fault of a single line disrupts minimal portion of the grid. Next, there is balancing (or whatever that is called. Balancing is having redundant coal/nuclear reactor to balance quick and unpredictable output variations from e.g. solar/wind, variations in demand quicker than output increase rate of a plant, etc.) - grid designers/operators must ensure that energy flows more or less equally through out the grid. Similar problem to wireless mesh networking - one needs smart routing to avoid bottlenecking at single link.
Some of electric grid and computer network problems are almost the same. While users can say, well 10 years ago we had single desktop at each home unit and were happy. Now we have the problem that each home member has laptop, smartphone, tablet. We will install wireless routers and ISP can "ADD MOAR FIBER!!1". Not that simple, right?
I'm kind of surprised that, if they're already assuming they can build the battery and make it small enough to fit in a car, that they don't suggest that they will be able to build a charging station for pretty cheap too.
But transporting the liquid maybe is just even cheaper still, if they assume more of a distribution center with the charging equipment and higher capacity electricity access.
This one is different by not having a membrane.
My impression is that the difference between flow batteries and fuel cells is that flow batteries are closed systems whereas fuel cells are open systems. Since this can be refueled, it sounds like an open system.
Edit: Your linked Wikipedia article answers my question. "A flow battery is a rechargeable fuel cell." I guess the distinction is not closed vs open, but rechargeable vs unspecified.
A flow battery is completely self contained.
Getting your oxidizer from the environment obviously helps with weight, but it comes with its own set of problems since it's hard to control purity.
The wikipedia definition kinda touches on this. Since everything is contained in the battery you can recharge it with just electricity.
In contrast a fuel cell will emit the waste (water usually), so you no longer have the raw material to recharge it anymore. (Although obviously you can just make more by collecting it from the environment - think emit the water, then electrolyze other water to recharge the battery.)
The whole "Breakthrough! Just add money!" thing is really tiresome not because it would be wonderful if it was as simple as just adding money, but because so very many people have abused it when they really had no idea at all about what the issues were with their technology.
I like the concept of flow batteries, and have read a number of interesting papers over the years on them. They solve a number of problems if you can get them to work and the instant recharge is perhaps the best one.
That said, a very good flow battery demonstrator project would be a set of solar panels (cheap these days), continually pumping electrolyte from a reservoir and 'charging' it (inverting its oxidation reaction). Coupled to a flow battery and a constant load.
If you can't build that, and show that by putting 'nX' load of solar cells in the loop, and continually run the base load 24x7, then you've got the basis for an actual breakthrough. Even doing it for a small "meaningless" load like 50 watts (1.2kWh / day), you will have demonstrated not only that your battery works but that it can be combined in a system that currently requires "previous generation" batteries.
And from that demonstrator you can make educated guesses about how much maintenance would be required for a larger scale system, how well the system performs 24x7, how to maintain it while it is operating, Etc.
Then you can say, for $X we estimate we could run a typical house off grid. For $Y we estimate we could provide Z MWhr of base load. If you can't build the 50W system though, it is unlikely you can build any system yet.
https://whova.com/embedded/subsession/icpma_201705/177114/17...
Still I would love to read how Dr. Cushman sees it working out.
[1] http://www.reuters.com/article/metals-vanadium-prices-idUSL4...
Purdue, as with MIT, tends to oversell their research a little bit (a lot). The difference is that MIT's overselling is believable whereas Purdue's wreaks of insecurity and overstating as posturing. As others have noted on a technical level...take it with a grain of salt. The current president (and ex-Republicant governor) Mitch Daniels has been pushing a really hard narrative of privatizing the university and its resources for corporate gain. He neeeeeeds this type of thing, whether or not it pans out.
* Presumably, you have to fully empty and then fill your tank?
Over twice as long to refill as for gasoline/diesel. (Still:
not terrible.)
* How do you get refunded for your partially used "fuel"?
I generally refuel around a quarter of a tank. In this case,
that means I'm sending back 25% unused fuel.
(Pump it out, analyze the mixture, provide credit? Seems seriously game-able.)
* Is the power output constant regardless of charge? Can I get 20kW
of output at 25% charge?A recharge should be pretty cheap. The national average cost for electricity is ~13¢/kWh, so refilling a 100 kWh battery would only be $13 of energy. Other costs - storage, maintenance, labor, land, etc - add to that, but you still aren't out that much. It's possible that you just pay full price regardless, since they are giving you totally fresh solution.
One of the most important things about flow batteries is that they're basically invariant with charge and scale, so almost certainly (until you really hit the dregs - you probably lose voltage at 4%).
What about solar panels on the roof? I found this article [1], and Elon Musk has said they'll "probably offer it as an option" [2].
I wonder how many extra miles you could get with that. If nothing else, it would be nice to know that you could slowly recharge your battery if you get stuck in the middle of nowhere.
Another idea - highways where you could drive while recharging. Maybe something similar to train tracks, or an overhead wire. Or wireless power transfer through the wheels, if that would be possible? (I don't think it is.)
[1] https://thinkprogress.org/prius-solar-roof-breakthrough-2b92...
I'm probably totally wrong here, but if the whole car was solar panels I would expect 600 watt to be generated. An electric car would need that for 0.8hrs or so to move one mile (0.44 kWh/mile?) plus acceleration.
So for every square meter of roof space covered in panels you can get a max of about 200 watts of power.
This is a lazy, handwavy characterization of the situation, but it paints the picture, it isn't much of a contribution as batteries head north of 50 kw-h.
At 90 degree incidence, after that it falls off as the co-sine of the angle. So if you don't track the sun it will drop considerably, you daily average compared to the ideal is more likely going to be between 7 and 12%.
A 100W solar panel typically generates about 400 Wh per day, and has an area of 0.7 m², weighs about 8 kg, and costs about $100.
Using the range and battery data for the Tesla S:
A 200 km daily commute (i.e. an hour each way) you would require ~35 kWh, and require 90 100W panels, or 60 m², weigh 700 kg, and cost $9000. Possible, but only as a fixed install, not on the car’s roof!
For touring, you could do 500 km per night (about maximum range for the 100 kWh Tesla S) and charge during the day, but would require 250 panels / 175 m² / 2000 kg / $25,000. You would require a trailer to carry them, and the set up & tear down each day would be laborious, but it would be possible and you could then travel indefinitely. A bit like what Mark Watney does in The Martian. If you were willing to spend multiple days charging for each 500 km leg, or only travel a couple of hours per day it would be even easier.
Edit: I just looked up The Martian and Watney had 18 kWh of batteries for his rover, 28 m² of panels (with longer days but less power), travelling a max of 90 km per day for over a month. So yeah.
1. would this be dispensed just gas? Pull up, pay, and pump it in?
2. But in this case you would also pump the old stuff out?
3. Is there any "prep" time needed for the solution? aka charging
I have a Tesla, and if I had to make a choice between a traditional battery and a battery I can fill instantly but can't fill at home, I'd take the traditional battery without hesitation. Faster charging on trips would be nice, but not worrying about it the rest of the time is even nicer.
Tesla owners are distinctly not representative of the average person's situation.
In otherwords, if you're adaptable to home charging, then you really want home charging. Makes perfect sense to also observe all current EV owners are adaptable to home charging, by definition.
So strictly speaking adding it expands the market to different kinds of EV owners who would treat it like a gas car, just with no direct emissions. If you can add this feature without sacrificing anything else, I'd say that's a very big deal.
I assume that in reality this tech is a decade of hard work away from even being usable in an EV, so we'll never see it made.
That's confirmation bias at best. You should ask why folks who don't buy Tesla (and buy cars at the same price point) decided otherwise.
There's really no point to exchanging the electrolyte in an EV, even a 45 minute charge while grocery shopping or eating is "one less stop."
* Refueling requires hooking up and exchanging hazardous materials (fluids).
* This assumes that there's a single universal electrolyte fluid.
* Variability in fluid quality / consistency (across areas and batches) / return materials fraud are problems.
* The less sealed nature of the batteries is probably a safety hazard (increased crash/fire risk, etc).
I think that the public would be better served by standardizing on a few /types/ of battery packs as physical interfaces, and having rapid 'tank replacement' stations (robots) and leased battery packs.
Innovation in storage tech and/or picking a pack sized for the expected use would allow for improvements and competition as well as changes in technology.
We'd need to know more about what type of chemicals are used in this battery, but glancing at what's involved for 'flow batteries' I'd make a /slightly/ educated guess that these would all be considered 'industrial' materials. You might see a public bus using them, but I doubt it would be safe to allow the average driver to self-refuel.
Gasoline is incredibly toxic, we are just accustom to it so we don't give it much though.
Worrying about quality control of the fluids is similar. The global energy industry is up to the challenge of reliably producing batches of chemicals that narrowly match a particular specification.
If you can get them looking into it enough to try to teach you about it (seems like human nature to want to correct people who are wrong) then you've won because they'll also pick up (without being told in ways that get their backs up) that they were also wrong and they can just quietly abandon that stand.
But honestly, for the last 10 or so years, I can't remember even ONE time that I've heard about "revolutionary new battery technology" and it arriving on the market soon after. Or ever.
Honestly, what happens to ALL those people? From genius 13-15 year old school students to established scientists -- did anyone try to contact them, say, one year later?
I am tempted to think that inventing a possible new revolutionary battery technology is closely correlated to suddenly teleporting far away from Earth.
(Not sorry for sarcasm)
One company I've been watching closely which at the same time has been secretive to say the least: http://www.amprius.com/ Their product is a li-ion battery with a silicon anode and apparently it works, because they put it into an actual device: http://www.imei.info/phonedatabase/79823-bluboo-x550/ (Note the massive 5Ah battery)
These guys generated quite a buzz back in the day: https://oxisenergy.com/ For now their product is sort of disappointing, but the lone fact that they harnessed this new chemistry is notable.
Last but not least IMO the most promising company among them all: https://www.eosenergystorage.com/ I remember when they were promising 6MWh/1MW stacks and 10k cycles instead of the 4MWh/1MW stacks with a lifespan of 5k cycles they are offering now, but the key thing is they are deploying them as we speak - actually, their total production for 2017 was sold out at the start of this year.
These 1MWh stacks are made from 12kWh modules, which sooner or later will be offered to individual customers.
From I gather from the websites, it seems these companies move to bigger batteries and stuff like making more reliable power supplies for machinery -- maybe partially-off-the-grid homes as well?
Does that mean they had no luck in minituarizing their tech to make it viable for smartphones, smartwatches, Bluetooth headsets or car audio systems -- generally a small consumer-grade battery?
I very clearly remember at least two separate cases of teenage Indian school students that managed to demonstrate a prototype of a very quick-charging battery that can hold 1000+ mAh, somewhere in the last 5 years. I am absolutely sure I've read such news.
However, last I heard about them, some corporation gave them free scholarship in an elite university... and after that, full radio-silence. Really makes me suspicous, you know. What the hell happens to these people? Don't they still want to revolutionize the world as they claimed they wanted to when they were teenagers?
In the case of OXIS their battery has pretty poor volumetric energy density, so while it's light(about as dense as water) it takes too much space.
On the other hand the Eos's battery has great volumetric/gravimetric parameters, but poor power density - to the point where if you short-circuit it it's just going to seep current for four hours.
They were planning on putting these batteries in cars, but for that they would need at least a 100kWh unit which would still require a small li-ion buffer for short power bursts.
> However, last I heard about them, some corporation gave them free scholarship in an elite university... and after that, full radio-silence. Really makes me suspicous, you know. What the hell happens to these people? Don't they still want to revolutionize the world as they claimed they wanted to when they were teenagers?
Sometimes the research simply goes nowhere. Take for example the case of Sakti3 and Dyson. Dyson bought their business, because it looked promising, but after over a year of silence abandoned the patents that came with it. Apparently the chemistry simply wasn't viable for commercial use.
There's a table of the currently known public chemistries near the bottom.
There are applications with better power density than Lithium based batteries (at the electrodes), but I don't know about how an overall solution would compare to a gasoline setup.
I think the only fair comparison in such a case would be to have a roughly standard car design and compare complete solutions (currently common petrol / diesel depending on vehicle size, hybrid (electric), full electric (batteries / 'flow batteries' of different types)).
* what is lifecycle of batt?
* cost (not $ cost, resource cost?)
* slave-made?
how much trans-national exploitation occurs to produce one such batt?
There are commercial flow batteries that use membranes.[1] One uses zinc-iron. The energy storage capacity is limited only by tank capacity, so you can fill big tanks using solar power or wind and draw it out later. Typical system is 288 kW/960 kWh, and occupies 6 shipping containers.
The same reason metal does not rust without water (the metal/oxygen is touching after all without a membrane) - you need a second path for the electricity, which is what the water does. (The water does not chemically do anything - it simply acts as a wire.)
I'm having visions of the battery liquid sloshing around while driving.
This seems neat, though I think often academics solve one problem in a lab and then imagine a whole string of other problems will easily be solved to get their product to market.
The guy said the biggest problem is "man power". I'm skeptical of this claim.
They haven't built anything other than a table top demo -- I'd of liked to see them build a unit that could power something significant. Stick one in a golf cart at least.
But neat and inspiring nonetheless.