I've used both Twilight and f.lux (rooted only) on Android in the past and Twilight's defaults are rough and needs too much fuss & attention to get the settings right. f.lux was buggy even tho I was rooted. "Night Light" is OK.
I can only make it come on and off at a certain time, and the color temp is just a slider with no numbers.
With f.lux, I can have day, evening, and night, and it adjusts automatically to my location. When I travel, I have to adjust the time on my phone.
All little things, but it shows how f.lux is polished and Night Shift is not.
My phone is jarring in the evening because it's way cooler than my display.
f.lux may live on as a MacOS and possibly Windows desktop app, but it's pretty much impossible as a mobile app now.
IMO Apple chose the aesthetic of less red shift and traded away the sleep-assisting benefits of a more pronounced shift.