While the idea of donating to a library is always good, I doubt the usefulness of giving a library books on completely outdated technology that 0.0001% of people still use. Have you ever been to a used book store or library? Their tech section is nearly useless. I would honestly not want more tech books from 2002 unless they're well respected and in some way still useful.
I'd find a way to recycle them. The sad part about tech books is that most of them become useless after five years, if not before.