This isn't limited to just MDN you can use it for Youtube, and other sites that support the query search string.
If you are having trouble finding the settings in Chrome to get to then simply
hit the 3 dots on the top right > settings > then at the top bar search for 'search' > Under the Search heading there will be a button labeled 'Manage Search Engines' click it > and read the article to see how to set it up.
If you have visited MDN before it will show up in the lower section. All you need to do is change the middle text box to mdn and save. otherwise the last box will need to be https://developer.mozilla.org/en-US/search?q=%s&w=3&qs=plugi... the first box is just a label used to display the search name you can leave it at default.
happy searchin!