There aren't just a handful of Ad networks, there are thousands if not millions out there. On top of that, they utilize each other to push out ads in a horrid rat king like incestuous jumble. Any payments to avoid ads served by these companies would require compensating all of these companies, the end result predictably would be movie studio accounting that leaves the content provider with nothing in the end.
This setup does nothing to address the privacy issues people have with companies like Google tracking their comings and goings. Google is still at the heart of this system and still knows everything about you. To get any benefit from this system actually requires you to embrace Google. People want to maintain their privacy, they don't want to login to Google to get rid of ads.
It's easy to envision a system utilizing a crypto currency and a digital wallet held by your browser that you fill occasionally and that prompts you to pay a site similar to the manner in which Location Services work simply based on a meta tag a site provider puts in their page head containing their wallet and request pay amount and schedule. It's impossible to imagine Google, Apple, Facebook, or anyone who wants in your pants to allow themselves to be cut out of a revenue stream by such a system. Companies like this are double dipping by charging everyone else to be the broker and also by being the service provider being paid.
I honestly don't know if an ad free web is allowable. It's technically possible but everyone who isn't the content creator is going to do everything they can to stop it form happening.