It's possible. I've had people older than me join me. I've got multiple startups under my belt.
The hardest part is not getting them to join you.. the problem is getting them to stick! Especially in the beginning at a bootstrapped startup without a salary. Simply put, they have other options -- a Real Job(tm) or career they can go back to; and those options start looking better and better when things are bumpy (esp at the beginning). But, you can compensate for that. (by aggressively compensating on actual profits.)
On that note...
If you're reading this thread and have lots of experience and looking to join a hot security startup, we're looking for both experienced and inexperienced rockstars/ninjas/10x/etc. Please email me at first.last at userify.com. We have specific needs in the areas of enterprise sales and marketing, as well as engineering, security, systems architecture, Go, Python, and we're also looking for a strong Windows lead.