Use `cal -m` if you want a week to start on a Monday. AFAIK Sunday is the (US centric) default.
bratch@serenity ~ $ LC_TIME=en_GB cal | head -n2
May 2017
Mo Tu We Th Fr Sa Su
bratch@serenity ~ $ LC_TIME=en_US cal | head -n2
May 2017
Su Mo Tu We Th Fr Sa