It's just the way this proof is often presented that leads people to believe that it only proves that at least one is irrational; but once you accept that there is one irrational number, you can "index" it and add it to your denumerable list (pretend it's rational, say) and then run the diagonlization argument again, yielding yet another irrational number. Do this ad infinitum. Or, rather, stop: this will not halt ;)
Other proofs prove that the rationals are not equinumerous to the reals, but that there is a one-to-one function from the rationals to the reals… but that's another story.
(EDIT: as I'm getting a lot of hate and downvotes for this, I suppose I could delete the comment. It was intended to try to clear matters up for the parent of this thread. It wasn't intended as a deep explanation of anything at all. Forgive my triviality.)