Another nice perk is working a banker you can call who understands the cash needs of startups. You can speak to a person in plain English about how your whacky business model needs to work. They see all sorts of new weird stuff, and they are conditioned to want to help you. The value of having someone understand the highs and lows of startup life, and who will go the extra mile to resolve any hiccups is subtle, but nice. Basically, a startup banker for startups is nice in the same way a farming banker is nice for farmers.
They can also help introduce you to investors. Having a banker on your side when you're raising capital is not trivial.
That is all that comes to mind.
Any big bank will give great service, there's nothing unique here anymore. They all want your company to succeed as it means more business for them.