For me the biggest value from my PhD came from the writing up. It is really, really, really hard to get from having "done all of the work" to writing a coherent, well defended thesis on it. You will get very good at spotting holes in arguments (particularly yours, but also other peoples). You will get a very real understanding of how much work is involved in getting from 95% to 100% finished. It's not directly valued in industry but I know that I benefit personally from my writing up experience.
And you get to call yourself doctor. That's nice.