Beyond VX, there exist a plethora of other analogous chemicals, namely the G-Series[2], VE[3], VG[4], VM[5], VR[6] and VP[7]. A notable commonality among these compounds is that very little is known about their effects outside of military research (ie not shared).
Given the military nature of these compounds, there is a reason to believe that this was a military assassination.
[1] https://en.wikipedia.org/wiki/Novichok_agent
[2] Sarin is a G-series agent https://en.wikipedia.org/wiki/Sarin
[3] https://en.wikipedia.org/wiki/VE_(nerve_agent)
[4] https://en.wikipedia.org/wiki/VG_(nerve_agent)
[5] https://en.wikipedia.org/wiki/VM_(nerve_agent)
[6] https://en.wikipedia.org/wiki/VR_(nerve_agent)
[7] https://books.google.com/books?id=DQw2hVGe0aMC&lpg=PA72&ots=...