The sun is the perfect light source for photosynthesis and temperature. I only use LEDs as a last resort for seed starting. Also LEDs don't provide the heat which plants really, really desire so you will end up needing to supplement with heating pads, incandescent bulbs, or external heating.
I accidentally raised my electric bill $100 one month last year when I used a small space heater to warm seeds.
I'm currently trying the following experiments:
* winter sewing basil using milk jugs outside in the snow
* sewing onions indoors and germinating them on top of my houses boiler.