Is there a reason you don't use the people switcher? https://support.google.com/chrome/answer/2364824?co=GENIE.Pl...
The option I finally chose to go with, is to install firefox on her computer as well. Firefox is for me, Chrome is for her. I'm an FF guy anyway. The main UX problem stands, though, it's too easy to be the wrong person.
Also I get to keep up to date with changes in firefox.
Further, I'd guess that even if you absolutely trust your SO not to violate your privacy, you might still reasonably distrust the platform they're working on, and you might not want to expose your account credentials on a platform that you don't directly control.
The icons and applications look sufficiently different that there's no confusion about what persona I am in which browser. And I can have all of them up at the same time.