http://www.pokerlistings.com/libratus-poker-ai-smokes-humans...
The above article spells out some of the details of the competition. The winrate (14.72bb/100) that the AI achieved over the 120k hand sample is almost certainly not due to luck. It is a huge winrate that most pros have to employ strong game selection techniques to achieve (only play against bad players).
Here's a layman's explanation of how a poker AI can be trained: http://www.pokersnowie.com/about/technology-training.html
And some details about the weaknesses resulting from how they've abstracted the game: http://www.pokersnowie.com/about/weaknesses.html