If you introduce another pipe, that pipe will immediately get saturated.
LA has a TON of infrastructure, tons of long, expansive 6 lane highways, HOV lanes, Express lanes, tons of wide boulevards with 2-3 lanes in each direction.
LA is massive on a scale people don't realize - it's not as crazy as when you go to Manhattan for the first time because it's not built up. But spend some time there and you will be impressed by how big that city is. Think of the suburb you grew up in - big parking lots, wide streets, strip malls.
LA is like a giant, oversprawled suburb with 16MM+ people in the metro area.
Not saying we should just say screw it and give up, but the answer here isn't more roads or highways or tunnels.
It's things like uber, public transporation, car shares, things that get cars off the road.