So, what about those stokke kneeling chairs (http://www.amazon.com/Varier-Variable-Balans-Kneeling-Natura...)?
Here's a thought experiment -- hold your arm straight out for 8 hours.
Does it hurt?
Yeah. So why would it be a good idea to keep your back unsupported all day?
One thing though, the one I've used isn't a rocking chair; it has wheels instead. The rocking may make a difference.