An introduction to mobile messaging and analysis of the Threema protocol [video]
media.ccc.de
media.ccc.de
On the other hand, the web client they're about to release _is_ open source.
Anyway, it's the most secure messenger at the moment, IMHO, and I love the fact that no phone number is required.
I particularly like their take on the verification levels using a traffic light metaphor - giving visual feedback on how well trusted a contact is on my list; I wish other clients would adopt it something similar and encourage more people to verify keys out of band.