EX: Ozone is not heathy, but it's useful in the upper atmosphere. It's formed in part from Nox compounds, but they both end up as N2 and O2 the two main components of the atmosphere. https://en.m.wikipedia.org/wiki/Nitrogen_oxide
PS: This seems unlikely to work well. However, one option to break up the heat inversion might be to change surface coloration over a relatively large area to create large updrafts / downdrafts.