I don't really stay on top of popularity of distros, but I'd be surprised if Gentoo is in the top 10, in terms of usage. But, when I say "major Linux distros", I mean, specifically: RHEL/CentOS, Ubuntu and Debian, as those are clear market leaders on the server (I mostly pay attention to the server space). Fedora, Mint, and maybe Arch comes into the picture for desktop, I guess? SuSE seems to be on the rise again. All of those are systemd, I think.
I guess one can argue about what level of popularity makes something a "major Linux distro". I, personally, wouldn't put Gentoo into that category, unless I saw some evidence of dramatic increase in its usage.