Yeah they are considerably thicker, not really for stability but to be effective at stopping large penetrating and explosive projectiles and even acting as tank traps.
They are also slower to deploy, tho if you do it properly you dig both the obstacle outer ditch (which makes the effective height of barrier too high to scale) and trenches as you fill them since the ground needs to come from somewhere.
That said to deploy concrete barriers you need a crane, when push comes to shove a squad with shovels can fill a hesco.
Some concrete barriers can also be higher than hescos, tho you can stack hescos without much trouble.
Overall if you are building an FOB all you need is a few flatbed trucks and a bobcat (small earth mover) to pretty quickly deploy hescos, concrete barriers need heavy trucks (which also means proper roads, you won't be driving a truck filled with concrete barriers over soft terrain) and you actually need engineers (as in the military definition, not academically educated ones) to deploy them.
In an urban environment concrete can make more sense tho, you can't dig ditched to increase the height, can't dig up the ground randomly, and since concrete barriers are thinner they are more easily deployed in urban environments and it's not like you have issues with logistics.
Although it wouldn't surprise me if the pentagon somehow managed to airlift these barriers from the US to Iraq to be deployed in Baghdad instead of just contracting the local concrete factories.