If you are a student, use the money you would have donated to StackOverflow to purchase a book or a tool that will help you to learn better and become an expert.
If you are an expert, contribute your time to StackOverflow (instead of money).
Money is easy to get compared to content. What helps StackOverflow grow is quality content.
I am also interested how they approach the subject of money:
> How much money we make is a direct proxy for how much we are helping our users. We focus on maximizing how we help users in order to make a great business. Very few companies have done this successfully, and we take great pride in the fact that we’re one of them.
Personally, I would love to see how this works out and I wish them well. Hopefully they can prove this model works well. Users need this model to work well for other businesses to adopt.