Can someone explain how pi holds up when base 8 math is applied?
In the case of 4/6 and 6/9 there is an agreed canonical way of designating that value, namely 2/3. In the case of pi there is similarly an agreed canonical way of designating the value, namely the symbol π.
Pi is just our name for the ratio of a circle's circumference to its diameter regardless of the base.
This is why it doesn't make sense for an intelligent species not to know what 'pi' is. It's an important concept that pops up immediately in basic geometry and just keeps popping up over and over all the way to general relativity and beyond.
Yes, an intelligent species may not know pi but they would not have progressed even to the point of basic geometry in the maths and sciences.