> Is there an equivalent guide to the compile-time representation of important constructs for those trying to learn C/C++?
Definitely. It was taught in school and there's pretty good guides for it online (maybe not caught up to c++11 and beyond, but the fundamentals are there). You're right that it is not readily available for most languages, but when you need to get serious about performance you either are going to have a guide or spend a lot of time looking at assembly/bytecode. To be fair, I'd probably still have to inspect generated code sometimes, but it's nice to have good instincts for how things run to guide your design/implementation so you can spend less time looking at assembly.