It's the nature of dense energy storage media to run into problems if the energy is allowed to be released too quickly, but the characteristics of Li-ion do make it more conducive to cause these type of incidents. Battery university has a nice explanation of the typical causes here:
http://batteryuniversity.com/learn/article/safety_concerns_w...
Also, "Charge and Catch Fire: A History of Exploding Batteries and Other Product Recalls":
https://www.thestreet.com/slideshow/13728952/1/samsung-s-bat...