Sure, but on the pragmatic hand, "regular" isn't super useful unless you're designing a language yourself. If you're parsing something, not understanding "regular" is going to hurt a lot less than attempting to use PCRE to do something it can't.
The sad thing is that the libraries use the same algorithms even if the expression doesn't contain backreferences. A while ago, Stack Overflow had a brief outage because of regular expression performance, although the expression that caused it didn't even use backreferences or other non-regular features:
http://stackstatus.net/post/147710624694/outage-postmortem-j...
In contrast, Google Code Search - when it still existed - supported regular expression searches over world's public codebases. One key ingredient making this possible was to only use proper regular expressions:
I'd argue that this is useful, even if you use it as part of a parser that doesn't just parse regular languages, as you'll have a slightly easier time reasoning about the time and space complexity of the construction.