Not really you can always mirror the wan/uplink port and do the capture on another box so even some time based / performance analysis won't show anything.
Port mirroring is enough to capture SSL traffic and to break weak SSL keys or if you have compromised the key of the destination services (w/ some caveats like no forward secrecy etc.)
And it doesn't prevents you from executing MITM attacks from upstream or just doing specific MITM attacks from within the TOR exit node later on.
But overall there is nothing you can do to ensure that your TOR exit node, your VPN gateway or even your ISP isn't reading your traffic other than to use encrypted tunnels everywhere and even then you are for the most part only moving the problem upstream.