This is interesting to me. A lot of what I know about posture indicates that once you are conscious of your bad habits, fixing them isn't all that hard. Something like this could very easily give people a clear indication of what their bad posture is a result of, and pretty quickly help them out of it. The low tech version of this is posture taping [0], which works, but is probably a considerably less attractive option to most people, and certainly less targeted.
[0] http://www.physioadvisor.com.au/health/taping-techniques-upp...