More importantly, since Poland was under Russian and German rule nobles were often dispossesed and persecuted.
Maria Skłodowska-Curie herself had to earn her living (mostly by being private tutor), as did her husband, parents and others.
So no, education was not rich women's entertainment, it was necessity.
I seriously doubt most of these women were living a life of leisure. Additionally, let's assume you are right: How on earth does that rebut my comment about educating people who desire to learn? Because surely the leisure class could have been bar hopping and throwing or attending wild parties instead of trying to learn something in spite of it being against the rules to get an education.
It doesn't, why should it?