Joke asides, one thing I've been trying to figure out for awhile is the limitation at which certain components/ systems broke down. Basically, something along the line of "given X records, this operations would take Y time, or would cause Z A B C problems". I've actually got developers friends asking me how fast a simple "SELECT * FROM X WHERE index=?" would take on a million row table, since they were surprised that some NoSQL DB could do a query on hundred million rows in a few seconds.
I guess that's part of why you only learned how to scale after having done it once.